Photosensitized production of functionalized and unsaturated organic compounds at the air-sea interface
نویسندگان
چکیده
منابع مشابه
Photosensitized production of functionalized and unsaturated organic compounds at the air-sea interface
The sea-surface microlayer (SML) has different physical, chemical and biological properties compared to the subsurface water, with an enrichment of organic matter i.e., dissolved organic matter including UV absorbing humic substances, fatty acids and many others. Here we present experimental evidence that dissolved organic matter, such as humic acids, when exposed to sunlight, can photosensitiz...
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We report on experiments that probe photosensitized chemistry at the air/water interface, a region that does not just connect the two phases but displays its own specific chemistry. Here, we follow reactions of octanol, a proxy for environmentally relevant soluble surfactants, initiated by an attack by triplet-state carbonyl compounds, which are themselves concentrated at the interface by the p...
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Direct spectroscopic evidence of the presence of organic phenolate ions at the air/aqueous interface has been established using the nonlinear spectroscopic technique of vibrational sum frequency generation (SFG). By probing the phenol C–OH and the phenolate C–O vibrational stretches, which occur in the range of 1200–1300 cm and are distinguishable, we have succeeded in determining the identitie...
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In this study, we evaluated photosensitized chemistry at the air-sea interface as a source of secondary organic aerosols (SOA). Our results show that, in addition to biogenic emissions, abiotic processes could also be important in the marine boundary layer. Photosensitized production of marine secondary organic aerosol was studied in a custom-built multiphase atmospheric simulation chamber. The...
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ژورنال
عنوان ژورنال: Scientific Reports
سال: 2015
ISSN: 2045-2322
DOI: 10.1038/srep12741